First of all, welcome to the CAC. I'm very glad to see another '75 L-48 on the forum.
The performer and performer RPM heads are basically identical, the main difference being the performer heads having provision for exhaust gas recirculation. If this is necessary for retaining the smog systems in your vehicle (depending upon state smog laws) then, by all means, don't hesitate to go with these heads. Bear in mind that there are a number of head manufacturers out there. Edelbrock makes a great product, but there are others to consider, such as AFR, Dart, etc.
If you don't mind, I would like to point out a few things to keep in mind. You didn't mention your final drive ratio. I will assume that you are running the stock TH400 transmission and 3.08:1 differential.
In order to keep from being disappointed in the performance, I would stick with heads that have a rather smallish intake size. Something like 170 CCs would be good. With a higher rear axle ratio, you want to keep your low end torque up. The smaller intake runners help cylinder filling at lower RPMs, which translates into low end torque.
Stock '75s have a horrendous compression ratio. They came with 76cc combustion chambers. Be sure to select heads with a 64cc combustion chamber. This will raise your compression ratio by one full point . . . maybe more. You'll like the results of that.
Next, be very careful of the cam selection. This is the area that will disappoint you the most. Too much cam and you will lose your low end . . . again, that is death for a high rear gear ratio. You launch will be sluggish and you will end up being disappointed. Think about what RPM range your engine normally lives in. With a high rear gear ratio, you need most of your power/torque between idle and 4500 RPM or so. So select a cam that gives you the most oomph in that range. Check out the Summit 1100 or 1101.
Make sure that you use new lifters. I would always recommend new pushrods with new lifters. With new heads, you may also need new pushrods of a different length than your old originals.
Roller rockers are not completely necessary, but are a nice benefit.
To help your launch, think about a mild stall converter . . . maybe a 2200-2500 or so. You'll be surprised at the difference.
I hope some of this helps. I'm no expert by any means, but I've been there, done that with my '75. Went through a lot of money and disappointment before I found a combination that I was really happy with.
Good luck,
Ron