Oh, that's a work of art! I always liked the tri-powers.
For the manifold:
Dry-fit your gaskets to establish orientation, and throw away the rubber seals for the front and back. You will need to get some "Great Stuff" Silicone gasket from the parts store.
Using silicone sealant, run a small bead around the coolant passages for the intake manifold on both sides of the gaskets and smear it smooth with your finger, and put a blob under the tabs at the ends of the gaskets where the block and heads mate. Then place the gaskets on the heads and run a continuous bead about 3/8" diameter along the mating surfaces on the block, front and back, between the heads to replace the rubber seals.
Then carefully lower the intake manifold in place, using a bolt on opposite corners as a guide to make sure the manifold locates squarely. Then put all your bolts in and hand tighten.
Then, following the assembly manual, torque the manifold bolts according to the torquing sequence to the proper torque.
It's important to do the assembly as quickly as possible to avoid skinning over the silicone sealant, but take your time and be careful not to pull the manifold up once it's placed, because the silicone should be compressed in a smooth motion to avoid voiding. Work careful, and take a beer break after the bolts are torqued.
Now the distributor:
Turn the crankshaft to TDC on the compression stroke so that both valves are closed on the #1 cylinder. The look at your distributor cap and determine where the #1 plug wire is. There are numbers on the retainer for the wire boots to help
Put a new gasket on the distributor.
The gear on the distributor shaft will engage the gear on the camshaft when you lower the distrubutor into the manifold as you get it about 1-1/2" from bottoming out. And the oil pump shaft will mate with the end of the distributor shaft.
Now, you ask, how do I get these to line up? Trial and error is the way it works.
When you drop the distributor in, the gear will cause it to rotate about 18 degrees, so the idea is to get it to point directly at the #1 plug tower on the cap when it is all the way down, so you have to estimate how many teeth to rotate it initially to have it end up there when it's all the way down on the manifold. Try it, and re-adjust if it overshoots or undershoots.
If it does not drop down even with the manifold surface, the oil pump shaft needs to be rotated a little so that the slot lines up with the distributor shaft. Once again it's a trial and error process. Use a long wide bladed screwdriver to rotate the oil pump shaft a little at a time until everything mates up.
So when you are finished, the rotor on the distributor will be pointing at the #1 plug wire tower with the cap on, and the distributor will be setting down all the way onto the manifold. Then install the holddown clamp and bolt to hold the distributor down but leave it loose enough for the distributor to turn for timing purposes.
Let everything set overnight to let the silicone cure in place. It will be ready to refill with coolant in the morning.
Have fun!