Alternators produce electric power to run the electrical systems on the car. There is also a battery, but that is just to store power (to start the car, as well as to run accessories like the radio, when the engine is off).
A car with a carb has limited electrical needs. Ingition system, lights, guages, radio, etc.
A fuel-injected car has added needs. Draw from the computer is there, and the fuel injectors, themselves, draw a pretty decent amount of power. The electric fuel pump also draws quite a bit. It all adds up to the need for an alternator which can produce more power (about half again as much as the stock alternator can handle).
There are two ways to increase power: more volts, or more amps. Now, voltage is sort of like water pressure, and amperage is sort of like the physical amount of water which flows. Either could be increased in order to increase the power, but it is much easier to just increase the amperage, and leave the voltage the same. Again using the water analogy, imagine a pair of faucets attached to the same pipe. And then imagine that you need more water out of one faucet. If you increase the pressure, you may cause leaks. If you increase the amount of water that flows through the pipe, the second faucet can draw more of it, and you don't risk leaks.
The same way, increasing the voltage can cause damage to some components, due to the increased electrical "pressure." Increasing the amperage merely allows the components that need more power, to draw it, without forcing more on others.
So, you keep your stock 12-volt (really, 13.4V, but that's just a matter of labelling) system, and increase the amperage rating of the alternator.
Joe