1) Read statement "LLC5" made above
2) A compression gauge will be inaccurate at pressure levels that low. If you're going to measure back pressure you need a back pressure gauge or any air pressure gauge which a scale of 0-10 psi or so.
3) Nominal back pressure ahead of the main cat may vary widely depending on the cat and the design of the system.
4) The above test will not take into account the precats or "pup cats" which often are located ahead of the O2Ses and are usually more restrictive than the main cat.
My suggestion is that you take the car to an exhaust fabricator, scrap the precats and, if the main cat fails the "in-and-out temp test" suggested by "LLC5" replace the 24-year old main cat with a new unit.