I will agree with Jim. The older Vette's, as any old car, are very tons of fun to work on. Unlike Jim, I have been a shade tree mechanic for the past 20 years and have worked on just about everything. However, the Vette is a lot of fun to work on. It is surprising how easy they are to work on. Yes, they are much tighter than the later C4-C5's, especially in the engine compartment. But I have only run into a few areas where they are a real challenge.
If you are going for a daily driver, let me offer this. The later models (C4-C5) that have really updated technology and computer control will probably prove better for a daily driver. Even a later year C3 would be a good option, for this reason and to keep your cost down. This is not to say an early C3 is not reliable. I have driven many an early 70, late 60 car or truck daily with no poblems. However, the later technology engines tend to be more mild mannered than earlier small blocks for daily use. However, with this said, you can learn to work on an earlier model car easier in my opinion.
I know all of this can be confusing. There are arguments on either side of the coin. For what you want, I would say stay late C3 model year. This will give you both worlds. Some computer control and will still be fairly easy to learn to work on.
Good luck