In general, you should have a four wheel alignment done to make sure that the whole job is done right. A good shop will have a Snap-On laser alignment stand. If they don't, go somewhere that does.
Do not go to a dealer or tire shop!!!!!
The first step is to inflate all tires to the proper pressure.
The next step is to align the rear wheels. In most cases the rear end will not have to be touched unless something is bent. It involves removing the shims from the rear trailing arm mounts, but it will tell you if you need to replace a bent trailing arm. The rear wheels will be used as a reference axis to align the front wheels.
Once the rear wheels are referenced, the camber, caster and toe in is measured on the front wheels by turning the wheels lock to lock on a turntable to measure the angles of each setting. Camber and caster is adjusted by removing or adding shims to the upper and lower A-arms, and can be affected by spring wear over time or changing tire diameter.
The final step is to center the steering wheel and adjust toe-in to specs.
You should get a printout to show the Before and After alignment numbers. The final numbers should be within +/- 1/32" according to the posted specs. for your model
Your printout should look something like this:
-----------------------Left Front Readings-----------------Right Front readings
-----------------------Initial-----Final-------------------------Initial-----Final
Caster----------------+2.36-----+2.48-----------------------+2.36-----+2.48
Camber---------------+0.08-----+0.08----------------------(-0.16-----+0.08
Toe--------------------+3/16-----+1/8-----------------------+9/32-----+1/8
------------------------Left Rear Readings--------------------Right Rear Readings
Camber----------------+0.28-----+0.28---------------------+0.16-----+0.16
Toe---------------------+1/4------+1/4----------------------+1/16-----+1/32
So when you're all finished you will see what your alignment was and what it is after the alignment.
I have a guy that lets me stay and talk to him while he does my alignments, and he taught me the step-by-step process on several of my cars. Mark's Alignment-Webster, NY.
It should drive like a brand new car when it's all finished. If not, you got ripped off.
I hope you have good luck with your Vette.