self aligning refers to roller rockers. the tip has a roller on them, and wants to twist off the top of the valve. Self aligning rockers have two mini 'guides' (don't mix up these guides with valve guides) on the side of the roller tip, so it sorta seats up on to the top of the valve, to stop it from twisting off. there is a raised portion on top of the valve, that the rocker seats to with self aligning.
you really gotta see it to understand... if you look at the rocker head in, right at the roller tip, it will look like l-l the dash being the roller, and the l 's being the guides. a standard roller tip looks like l_l so ther is nothing hanging over to 'grab' the valve.