Took the heads off my '73 L48 last Fall for a rebuild while leaving the engine in the car. Actually the job was easier than I had expected although I don't have a/c. From memory, the main steps were:
1. set engine to TDC (useful for getting the distributor back in correctly)
2. disconnect battery
3. remove hood
4. drain off coolant
5. label plug wires, then disconnect from sparkplugs, undo wire from coil and tach cable. Remove distributor.
6. remove valve covers, rockers and push rods
7. remove alternator
8. disconnect fuel line from carb (catch the gas that will spill)
9. disconnect throttle linkage
10. unbolt manifold, in reverse order to torquing up (start outside and move inwards). I left the carb on the manifold.
11. unbolt exhaust manifolds. Actually I have headers - they were awkward to get out the way of the head bolts.
12. undo head bolts. Be very careful to follow the reverse of the the tightening sequence. Lift off heads.
Three additional tips:
#1. take LOTS of photos
#2. be sure to keep dirt out of the valley between the heads.
#3. clean everything very thoroughly.
Now, just out of curiosity, why do you want to remove the heads?
'73