Hib Halverson
Technical Writer for Internet & Print Media
Quaker State Quote...
The use of ZDDP in motor oil has seen a gradual decline since 2001 in order to minimize or eliminate clogging of oxygen sensors and catalytic converters in modern cars due to volatile phosphorus. Prior to 2001, the typical concentration was roughly 1300 to 1400 parts per million (ppm) of ZDDP. However, since 2001, modern passenger cars have required oils with lower viscosity to reduce power loss and increase gas mileage, but achieving these lower viscosities with higher concentrations of ZDDP is difficult.
The proprietary low¿volatility ZDDP technology used in Quaker State Defy motor oil significantly reduces the amount of volatile phosphorus, while retaining its anti¿wear protective behaviour and antioxidant performance. Quaker State Defy has a ZDDP composition of 1200ppm, a more than sufficient amount to stand up to the most aggressive engine profiles.
What a bunch of marketing BS. Great reason to not buy Quaker State products.
First, ZDDP does not "clog" oxygen sensors nor cats. The phosphorous which results when ZDDP breaks down at high temperature at the lobe/lifter interface and then is burned by the engine during oil consumption, slowly reduces the potency of the catalytic reactant in a converter but it doesn't "clog" the cat. The EPA wanted cats to last 150,000 miles so it pressured the oil refining industry to reduce–but not eliminate–phosphorous from EP additive packages in engine oils for gasoline engines.
Second, phosphorous is not "volatile". It won't explode or burn rapidly. What an idiotic statement.
Third, the concentration of ZDDP has little or nothing to do with viscosity. You can have a 5W30 with 1200 ppm phosphorous and you can have a 15W50 with 800 ppm phos.
As for ZDDP being "used up" it is true that the EP additives in engine oils have a finite life as they are chemically broken down by the running engine in the lubrication process, however, this doesn't happen rapidly. If your oil change interval is 7500 miles, you might have a problem with inadequate EP lubrication at say 10,000 or 12,000 miles.
The information Shell offered is generally correct---for stock flat tappet camshafts and aftermarket cams with mild profiles and modest spring pressures 800-1000 ppm phos is plenty. Aftermarket cams with more aggressive profiles and higher spring pressures need 1000-1200. The most aggressive flat tappet cams running very high spring pressures need 1200-1400. I'll add that in odd applications, such as NASCAR Sprint Cup, which run incredible flat tappet cams, super high spring pressures and 9000+ rpm, besides oil with higher phosphorous concentrations, they're also using some pretty exotic parts such as tool-steel flat tappets and special camshafts.
You will find it sometimes can be difficult to find the phosphorous the actual content of some brands of oil.