#1, you will have a stinky rich idle with the combo you are running. You will for the most part have to get use to that, and all you can really do is turn the fuel pressure down, and turn the tps down to minimum at idle.
#2, You need to set your timing to the peak performance mode. Now that you have a scanner it is fairly easy. You need a co-pilot.
Fire up the car and get it to running temp. Bring your distributor wrench with you. Go out and run the car hard holding at load as long as possible. Watch the knock retard value on the scanner. You want to keep adjusting the timing to where you get just a tad of retard at WOT under a hard load. This is with premium fuel. This is how you know the max you can run. Anything lower is not enough timing, and anything higher will result in a loss of power as the knock retard is kicking in.
#3. To set the fuel pressure, get your co-pilot again. Get it warmed up, and go thrash the car hard. Watch under WOT for the O2 voltage to be at 860. More than 860 and you are too rich, less than that and you are lean. As you guessed it, this could change your timing setting, so you may be doing both at the same time. You will give more fuel pressure if WOT runs are netting less than 860 mv, and turn it down if WOT runs are netting more. In my 90 vette, the best I can do is right at 900 mv, and that is with stock injectors and a stock chip.
#4, try to have fun with it, and accept the fact it will never again have the smooth clean burning trouble free characteristics of a nice stock L98. You now have a mix match of parts and technology and they don't always work together at all time.
#5, Watch your TPS voltage, and for max performance, try to adjust it to reflect as close to 5 volts as possible at WOT. This will have to be balanced against your idle value that should not exceed .65 volts to keep it from getting tooo rich.